Online Seminar Announcement: Thursday 2 July 2020

Due to the cancellation of many scientific conferences, the AUCAOS committee is pleased to announce an online seminar series. We intend to run seminars on the first Wednesday of every month until normal conferences can resume.

Date: Thursday 2 July

Time:
1pm (QLD, NSW, ACT, Vic, Tas)
12:30pm (SA, NT)
11am (WA)
3pm (New Zealand)

Click this link to join the meeting: https://jcu.zoom.us/j/96575282919

Seminar schedule
Each talk is 20 minutes duration followed by approximately 5 minutes for questions and discussion.

Time (QLD time, adjust as needed): Presentation:
1:00 – 1:25pm Hybrid organic/inorganic chromophores

Dr Nathaniel Davis
Victoria University of Wellington

Luminescent light harvesting chromophores have the potential to improve many optoelectronic technologies, such as photovoltaics, LEDS, lasers and luminescent solar concentrators. Our research into the creation of artificial light-harvesting antenna complexes aims to disrupt the current chromophore technology. The current state of the art chromophores can be split into two types: 1) Organics, which suffer heavily from instability and reabsorption; and 2) Inorganics, which solved many of the problems inherent with organic emitters in terms of stability and reabsorption but require complex surface treatments to improve their luminescent efficiency (LE). We aim to combine the beneficial properties of both these systems into a single hybrid chromophore. This will act to improve the LE of the hybrid particle and reduce reabsorption losses.
The science behind attaching chromophores to nanocrystals and studying the subsequent photophysics is in its infancy. We envision two options forward, that would promote the field, both based on the replacement of ligands on a nanocrystal that offer colloidal stability with ones that add additional optoelectronic properties. 1) Energy transfer from the ligand into the nanocrystal, which will have potential applications for increased solar absorption, efficient transport of excitations, and singlet fission. 2) Coupling a highly luminescent molecule to a nanocrystal, avoids the complex surface passivations (treatments) required by current state-the-art nontoxic emitters and offers the potential for upconversion of light.This talk will look at our recent success with caesium lead halide nanocrystals.

1:25 – 1:50pm Dicyanovinyl-based fluorescent sensors for dual mechanism amine sensing

Dr. Guanran Zhang
University of Queensland

Food wastage due to spoiling is a global economic issue and contributes to over-farming and overfishing with real environmental consequences. Smart food packaging is a promising solution to this problem, the idea of which is to utilize responsive sensors that allow direct monitoring of the gasses released from food as it spoils and provides a visual indicator to the consumer. Here we report two dicyanovinyl-fluorene-benzothiadiazole-based fluorescent compounds, K12 and K12b, both of which showed rapid response to biogenic amines via two independent mechanisms. When primary alkyl amines were present in solution, they underwent Michael addition with the dicyanovinyl group of the sensing material, resulting in rapid color change. The reaction products of K12 and K12b with primary amines also showed a decrease and increase in the fluorescence quantum yield, respectively, enabling a unique dual-sensor array with turn-off/turn-on response. In addition, fluorescence quenching via photoinduced hole transfer was observed in the solid-state sensor films with a wide range of primary, secondary and tertiary amines, enabling rapid and sensitive detection of amine vapors. Finally, as a proof-of-concept integrated packaging sensor, soft membranes incorporating K12 and K12b were prepared and showed rapid response to primary amine vapor.

1:50 – 2:00pm Open discussion

 

During the seminar:

  • Please keep your microphone muted unless you are speaking. This is to reduce the background noise and avoid disrupting the presenter.
  • You will be automatically muted when you join the virtual meeting room. To speak, you will need to unmute yourself by using the audio controls in the lower left of the Zoom window.
  • If you have not used Zoom before, then it is recommended that you join 5 minutes before the starting time to ensure that you have your software set up correctly.

Please be aware that the talks will be recorded and posted on the AUCAOS website.

Previous seminars

Previous seminars can be viewed here: https://seminars.aucaos.org.au/

Call for abstracts

Seminars are held on the first Wednesday of each month.

In the spirit of building a community in these challenging times, you are encouraged to give a talk. Do you have a talk that you would have given at a conference that was cancelled? Please consider adapting that talk for this format.

Submit abstract by email to bronson[dot]philippa[at]jcu[dot]edu[dot]au.


Online Seminar Announcement: Thursday 4 June 2020

Due to the cancellation of many scientific conferences, the AUCAOS committee is pleased to announce an online seminar series. We intend to run seminars on the first Wednesday of every month until normal conferences can resume.

Date: Thursday 4 June

Time:
1pm (QLD, NSW, ACT, Vic, Tas)
12:30pm (SA, NT)
11am (WA)
3pm (New Zealand)

Click this link to join the meeting: https://jcu.zoom.us/j/99887544733?pwd=TVk1ZFl3WGtSWHJmMTM3dG9BVk1jQT09

Seminar schedule
Each talk is 20 minutes duration followed by approximately 5 minutes for questions and discussion.

Time (QLD time, adjust as needed): Presentation:
1:00 – 1:25pm An introduction into synthetic molecular motors

Jos Kistemaker
The University of Queensland

Scientific advances made in the last three decades, inspired by Nature’s example, has led to a diverse collection of synthetic molecular machinery. A prominent example of this machinery is the molecular motor developed by Feringa and co-workers which is based on a light driven overcrowded alkene. The study of several generations of molecular motors and their properties have had primarily academic merit, however, later developments have shown that these nanomachines can be used to do actual work and might prove to be the driving force in the transition to actual applications.
This talk will provide an introduction into the field of synthetic molecular motors with an emphasis on light driven rotary motors. The role of autonomy and chirality in different designs will be highlighted and several examples will be used to showcase the expression and translation of these features to other groups, molecules and larger scales.

1:25 – 1:50pm Electronic coupling: A significant contributor to electron transfer between similarly structured surface-bound porphyrins and Co2+/3+ complex electrolytes

Mr Inseong Cho
University of Wollongong

Electronic coupling is often assumed to play a minor role in interfacial electron transfer (ET) between similarly structured electron donors and acceptors. To check this assumption, we investigated the ET kinetics between four surface-bound free-base and Zn porphyrins and five Co2+/3+ complexes redox mediators with different ligands using transient absorption spectroscopy (TAS). The ET rates measured in this work are the fastest reported in the literature for surface-bound molecules and donors dissolved in electrolytes. By using a novel sub-ns TA setup, the importance of enhanced TAS time-resolution is demonstrated. Fitting the measured ET rate versus –ΔG resulted in poor fits with unrealistic trends in reorganisation energy values. This is explained by up to 60% variation of the electronic coupling (HDA) depending on the size of the alkyl-substituent of the Co2+/3+ complexes redox mediator. The HDA values obtained by assuming a constant reorganisation energy are shown to be dependent on tunnelling distances, characterised by tunnelling attenuation factor βel = 0.16 to 2.0 Å-1. This work suggests that changes in electronic coupling even by small structural modification previously considered negligible can be as significant as the effect of driving force.

1:50 – 2:00pm Open discussion

 

During the seminar:

  • Please keep your microphone muted unless you are speaking. This is to reduce the background noise and avoid disrupting the presenter.
  • You will be automatically muted when you join the virtual meeting room. To speak, you will need to unmute yourself by using the audio controls in the lower left of the Zoom window.
  • If you have not used Zoom before, then it is recommended that you join 5 minutes before the starting time to ensure that you have your software set up correctly.

Please be aware that the talks will be recorded and posted on the AUCAOS website.

Previous seminars

Previous seminars can be viewed here: https://seminars.aucaos.org.au/

Call for abstracts

Seminars are held on the first Wednesday of each month.

In the spirit of building a community in these challenging times, you are encouraged to give a talk. Do you have a talk that you would have given at a conference that was cancelled? Please consider adapting that talk for this format.

Submit abstract by email to bronson[dot]philippa[at]jcu[dot]edu[dot]au.


Online Seminar Announcement: Thursday 7 May 2020

Due to the cancellation of many scientific conferences, the AUCAOS committee is pleased to announce an online seminar series. We intend to run seminars on the first Wednesday of every month until normal conferences can resume.

Date: Thursday 7 May

Time:
1pm (QLD, NSW, ACT, Vic, Tas)
12:30pm (SA, NT)
11am (WA)

Click this link to join the meeting: https://jcu.zoom.us/j/95510880226?pwd=OEhnS2c1d3BGdkdTV1Mwd2F4V21QUT09

Seminar schedule
Each talk is 20 minutes duration followed by approximately 5 minutes for questions and discussion.

Time (East coast, adjust as needed): Presentation:
1:00 – 1:25pm Microstructure formation in solution-processed semiconducting polymer thin films
Prof. Chris McNeill
Monash University

Semiconducting polymers are interesting materials that are being developed for a wide range of applications including polymer field-effect transistors, polymer solar cells, and polymer light emitting diodes. The performance of such devices is strongly dependent upon the thin film microstructure of the active semiconducting polymer thin film. As semiconducting polymers are processed from solution, the resulting thin film microstructure is complicated and can be hard to control. In this presentation I will present research performed in my group aimed at understanding how microstructure forms in solution-processed semiconducting polymer thin films. A focus will be placed on the n-type naphthalene dimide-based polymer P(NDI2OD-T2) which exhibits a rich microstructure and good performance in field-effect transistors and polymer solar cells. The influence of molecular weight and processing conditions on thin film microstructure will be discussed, along with the impact of thin film microstructure on field-effect transistor performance. This talk will also feature a host of different synchrotron-based techniques that have been used to understand the polymer physics and microstructure of this system.

1:25 – 1:50pm Charge transport in disordered materials for photodetector applications
Dr. Almantas Pivrikas
Murdoch University

Non-crystalline disordered semiconductors such as organic molecules, polymers, nanoparticles offer great advantage for electronic devices where the novel physics as well is yet to uncovered. All these materials lack long range structural order and have one common feature – their electrical conduction is inferior compared to highly-crystalline inorganic semiconductors such as silicon because of orders of magnitude lower electron and hole mobilities as well as strong recombination rates. Yet, organic electronic devices made using these disordered materials have the performance comparable to their classical inorganic counterparts.
Photoconductivity and charge transport measurement techniques such as Time-of-Flight or Hall-effect are typically not applicable or unreliable to study the charge transport in these disordered systems. In this presentation the core problems with experimental issues will be explained and our novel techniques introduced. Our work relating to hot photocarrier utilization in photodetectors as well as the novel peculiarities of charge carrier recombination in crystalline and disordered semiconductors will be demonstrated.

 

During the seminar:

  • Please keep your microphone muted unless you are speaking. This is to reduce the background noise and avoid disrupting the presenter.
  • You will be automatically muted when you join the virtual meeting room. To speak, you will need to unmute yourself by using the audio controls in the lower left of the Zoom window.
  • If you have not used Zoom before, then it is recommended that you join 5 minutes before the starting time to ensure that you have your software set up correctly.

Please be aware that the talks will be recorded and posted on the AUCAOS website.

Call for abstracts

The next online seminar will be held on Thursday 4 June 2020.

In the spirit of building a community in these challenging times, you are encouraged to give a talk. Do you have a talk that you would have given at a conference that was cancelled? Please consider adapting that talk for this format.

Submit abstract by email to bronson[dot]philippa[at]jcu[dot]edu[dot]au.


Online seminar series

Due to the cancellation of many scientific conferences, the AUCAOS committee is pleased to announce an online seminar series. We intend to run monthly seminars until normal conferences can resume.

We are calling for speakers for the first seminar session. It is hoped that our speakers can adapt talks that they would have otherwise given at conferences that have been cancelled.

Date: Thursday 7 May
Time:
• 1pm (QLD, NSW, ACT, Vic, Tas)
• 12:30pm (SA, NT)
• 11am (WA)
Format: Zoom meeting link to be distributed. Each session will consist of 1 – 2 talks of approximately 20 minutes each, followed by discussion.

To be considered for a speaking slot, please write a title and short abstract for your talk and email to bronson[dot]philippa[at]jcu[dot]edu[dot]au. We are calling upon the community to pull together to ensure that we can continue scientific communication in these times. Please consider giving a talk.


Ivan Kassal Awarded Le Fèvre Medal

AUCAOS member Ivan Kassal has been awarded the 2020 Le Fèvre Medal from the Australian Academy of Science, recognising “outstanding basic research in chemistry by researchers up to 10 years post-PhD”.

For more information, including a video, please follow the links below:

https://www.science.org.au/opportunities-scientists/recognition/honorific-awards/early-career-awards/le-f%C3%A8vre-memorial-prize

https://www.science.org.au/opportunities-scientists/recognition/honorific-awards/honorific-awardees/2020-awardees#fevre


AUCAOS Symposium 2019

85 delegates from around Australia and NZ attended the third AUCAOS Symposium at Katoomba, New South Wales.

The talks included an exciting range of topics in the field of organic semiconductors, including a keynote presentation by Priv.-Doz. Dr. Alexander Colsmann of Karlsruhe Institute of Technology, whose talk was entitled, “Eco‐friendly solution processing of organic solar cells”.

We would like to thank our sponsors – Australian Centre for Advanced Photovoltaics (ACAP), ARC Centre of Excellence in Exciton Science, SCITEK Australia Pty Ltd, John Morris Group, AINSE, Lastek Pty Ltd and the Australian National Fabrication Facility, Queensland Node – once again for their kind contribution.


Paper co-authored by AUCAOS members selected as “Editors Pick” in Applied Physics Letters.

A paper co-authored by PhD student Stephen Sanderson and AUCAOS members Associate Prof. Bronson Philippa, Dr George Vamvounis, Prof. Paul Burn, and Professor Ron White entitled,

“Elucidating the effects of guest-host energy level alignment on charge transport in phosphorescent OLEDs”, has been chosen as “Editors Pick” in Applied Physics Letters.

See the following links for more details:

https://aip.scitation.org/doi/10.1063/1.5131680

https://aip.scitation.org/topic/collections/editors-pick?SeriesKey=apl


Associate Professor Shih-Chun Lo and Associate Professor Ebinazar Namdas awarded Discovery Project for 2020

Associate Professor Shih-Chun Lo and Associate Professor Ebinazar Namdas have been awarded an ARC Discovery Project Grant in collaboration with Professor Adachi at Kyushu University, Japan.

Their research aims to apply new materials design theory in order to develop new classes of highly efficient materials and overcome device efficiency roll-off issues for next-generation transparent electronics.

For more details see: https://rms.arc.gov.au/RMS/Report/Download/Report/a3f6be6e-33f7-4fb5-98a6-7526aaa184cf/208


Paper co-authored by Prashant Sonar selected as “Hot Topic” in Advanced Materials

A paper co-authored by AUCAOS member Associate Prof. Prashant Sonar et al, entitled

“Developments of Diketopyrrolopyrrole‐Dye‐Based Organic Semiconductors for a Wide Range of Applications in Electronics”, has been selected as a “Hot Topic” in Advanced Materials.

See the following links for more details:

https://onlinelibrary.wiley.com/doi/full/10.1002/adma.201903882
https://onlinelibrary.wiley.com/doi/toc/10.1002/(ISSN)2199-160X.hottopic-organicelectronics


Paper co-authored by Soniya Yambem and Prashant Sonar selected as “Hot Topic” in Advanced Materials

A paper co-authored by AUCAOS members Dr Soniya Yambem and Associate Prof. Prashant Sonar et al, entitled

“Biowaste‐Derived, Self‐Organized Arrays of High‐Performance 2D Carbon Emitters for Organic Light‐Emitting Diodes”, has been selected as a “Hot Topic” in Advanced Materials.

See the following links for more details:

https://onlinelibrary.wiley.com/doi/full/10.1002/adma.201906176
https://onlinelibrary.wiley.com/doi/toc/10.1002/(ISSN)1521-4095.hottopic-carbon


Paper selected by Physical Chemistry Chemical Physics as ‘2019 HOT Article’

A paper published by PhD student Mohammad Babazadeh, Associate Professor David Huang, and Professor Paul Burn in Physical Chemistry Chemical Physics on “Calculating transition dipole moments of phosphorescent emitters for efficient organic light-emitting diodes” has been selected by the journal as a 2019 HOT Article. The research in the paper provides new insight into the role of molecular geometry and environmental effects on the orientation of the transition dipole moment, which plays a key role in determining the efficient of out-coupling of light from organic light-emitting diodes.


Associate Professor Prashant Sonar Wins Funding Grant with Indian Institute of Technology, Kharagpur

Associate Professor Prashant Sonar has received a funding grant (90, 000 AUD) with Indian Institute of Technology Kharagpur on “Inorganic-Organic Hybrid Flexible Solar Cells for Large Area Applications” under the Scheme for Promotion of Academic and Research Collaboration (SPARC).
Out of 282 proposals, 42 were shortlisted from Australian Universities (almost 14%), further strengthening research collaboration between India and Australia.
The list can be found here:
https://sparc.iitkgp.ac.in/apProposal_list.php